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two.2]decane Main and defining the geometry of the exocyclic double bond. The activation energies of formation with the vinyl-gold intermediates have been calculated and disclosed a silyl enol ether with an unprotected indole moiety as a suitable precursor to the Toste cyclization. This 6-stage synthesis didn't include any nonstrategic redox manipu
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two.2]decane Main and defining the geometry from the exocyclic double bond. The activation energies of development in the vinyl-gold intermediates were being calculated and disclosed a silyl enol ether by having an unprotected indole moiety as an appropriate precursor for that Toste cyclization. This 6-move synthesis didn't entail any nonstrategic